Poly[[[diisothiocyanatocobalt(II)]-bis[μ-4-tert-butyl-2,6-bis(1,2,4-triazol-1-ylmethyl)phenol]] dimethylformamide disolvate dihydrate]

Poly[[[diisothiocyanatocobalt(II)]-bis[μ-4-tert-butyl-2,6-bis(1,2,4-triazol-1-ylmethyl)phenol]] dimethylformamide disolvate dihydrate]

Blog Article

In the title compound, {[Co(NCS)2(C16H20N6O)2]·2C3H7NO·2H2O}n, each CoII ion located on an inversion center is six-coordinated by four equatorial N atoms from four different 4-tert-butyl-2,6-bis(1,2,4-triazol-1-ylmethyl)phenol (L) ligands, and by two N atoms from two click here axial thiocyanate anions [Co—N = 2.104 (3)–2.144 (3) Å].The metal centres are connected via the bidentate L ligands into two-dimensional polymeric layers parallel to bc plane.

The dimethylformamide chorulon hcg and solvent water molecules participate in intermolecular O—H.O and O—H.S hydrogen bonds, which consolidate the crystal packing.